High temperature determination of the rate coefficient for the reaction H2O + CN → HCN + OH

The rate coefficient, k, of the reaction has been determined in the temperature range 2460–2840 K using a shock tube technique. C₂N₂? H₂O? Ar mixtures were heated behind incident shock waves and the CN and OH concentration time histories were monitored simultaneously using broad-band absorption near 388 nm (CN) and narrow-line laser absorption at 306.67 nm (OH). The rate coefficient expression providing the best fit to the data was with uncertainty limits of about ±45% in the temperature range 2460–2840 K. The rate coefficient of the reverse reaction was calculated using detailed balancing, and its extrapolation to lower temperatures was compared with previously published results.     

Remarks on a conjecture on certain integer sequences

Summary The periodicity of sequences of integers <InlineEquation ID=IE"3"><EquationSource Format="TEX"><![CDATA[<InlineEquation ID=IE"4"><EquationSource Format="TEX"><![CDATA[<InlineEquation ID=IE"5"><EquationSource Format="TEX"><![CDATA[<InlineEquation ID=IE"6"><EquationSource Format="TEX"><![CDATA[<InlineEquation ID=IE"7"><EquationSource Format="TEX"><![CDATA[<InlineEquation ID=IE"8"><EquationSource Format="TEX"><![CDATA[<InlineEquation ID=IE"9"><EquationSource Format="TEX"><![CDATA[<InlineEquation ID=IE"10"><EquationSource Format="TEX"><![CDATA[$]]></EquationSource></InlineEquation>]]></EquationSource></InlineEquation>]]></EquationSource></InlineEquation>]]></EquationSource></InlineEquation>]]></EquationSource></InlineEquation>]]></EquationSource></InlineEquation>]]></EquationSource></InlineEquation>]]></EquationSource></InlineEquation>(a_{n})_{n\in\mathbb Z}$ satisfying the inequalities <InlineEquation ID=IE"1"><EquationSource Format="TEX"><![CDATA[<InlineEquation ID=IE"2"><EquationSource Format="TEX"><![CDATA[$$]]></EquationSource></InlineEquation>]]></EquationSource></InlineEquation> 0 \le a_{n-1}+\lambda a_n +a_{n+1} < 1 \ (n \in {\mathbb Z}) $$ is studied for real $ \lambda $ with $|\lambda|< 2$. Periodicity is proved in case $ \lambda $ is the golden ratio; for other values of $ \lambda $ statements on possible period lengths are given. Further interesting results on the morphology of periods are illustrated. The problem is connected to the investigation of shift radix systems and of Salem numbers.     

Kinetics and mechanism of the oxidation of sulfite by chlorine dioxide in a slightly acidic medium

The sulfite-chlorine dioxide reaction was studied by stopped-flow method at I = 0.5 M and at 25.0 +/- 0.1 degrees C in a slightly acidic medium. The stoichiometry was found to be 2 SO(3)(2-) + 2.ClO(2) + H(2)O --> 2SO(4)(2) (-) + Cl(-) + ClO(3)(-) + 2H(+) in *ClO(2) excess and 6SO(3)(2-) + 2*ClO(2) --> S(2)O(6)(2-) + 4SO(4)(2-) + 2Cl(-) in total sulfite excess ([S(IV)] = [H(2)SO(3)] + [HSO(3)(-)] + [SO(3)(2-)]). A nine-step model with four fitted kinetic parameters is suggested in which the proposed adduct *SO(3)ClO(2)(2-) plays a significant role. The pH-dependence of the kinetic traces indicates that SO(3)(2-) reacts much faster with *ClO(2) than HSO(3)(-) does.     

A 2D kernel determination problem in a visco-elastic porous medium with a weakly horizontally inhomogeneity

We consider a system of hyperbolic integro-differential equations of SH waves in a visco-elastic porous medium. In this work, it is assumed that the visco-elastic porous medium has weakly horizontally inhomogeneity. The direct problem is the initial-boundary problem: the initial data is equal to zero, and the Neumann-type boundary condition is specified at the half-plane boundary and is an impulse function. As additional information, the oscillation mode of the half-plane line is given. It is assumed that the unknown kernel has the form K(x,t)=K₀(t)+ϵxK₁(t)+…, where ϵ is a small parameter. In this work, we construct a method for finding K₀,K₁ up to a correction of the order of O(ϵ²).     

Diophantine equations with products of consecutive members of binary recurrences

We prove a finiteness result for the number of solutions of a Diophantine equation of the form \(u_n u_{n+1}\cdots u_{n+k}\pm 1 =\pm u_m^2\), where \(\{ u_n\}_{n\ge 1}\) is a binary recurrent sequence whose characteristic equation has roots which are real quadratic units.     

Unexpected formation of higher polythionates in the oxidation of thiosulfate by hypochlorous acid in a slightly acidic medium

It has been clearly shown that not only tetrathionate but also pentathionate or even higher polythionates is formed in the oxidation of thiosulfate by hypochlorous acid in a slightly acidic medium. In thiosulfate excess, the absorbance-time curves registered at 250 nm may go through a maximum followed by a minimum, suggesting the presence of a short-lived absorbing intermediate proposed to be S(2)O(3)OCl(3-). Matrix rank analysis (MRA) studies have revealed that altogether five independent absorbing species are present in the wavelength range 240-400 nm. A kinetic model is suggested to take all of the experimental observations into account.     

Bin covering with a general profit function: approximability results

In the recent paper (Benk? et al. 2010) we introduced a new problem that we call Bin Packing/Covering with Delivery, or BP/CD for short. Mainly we mean under this expression that we look for not only a good, but a “good and fast” packing or covering. In the present paper we investigate the offline case. For the analysis, a novel view on “offline optimum” is introduced, which appears to be relevant concerning all problems where a final solution is ordering-dependent. We prove that if the item sizes are not allowed to be arbitrarily close to zero, then an optimal offline solution can be found in polynomial time. On the other hand, for unrestricted problem instances, no polynomial-time algorithm can achieve an asymptotic approximation ratio better than 6/7 if $P\ne NP$ .     

An efficient solution approach for real-world driver scheduling problems in urban bus transportation

The driver scheduling problem in public transportation is defined in the following way. There is a set of operational tasks, and the goal is to define the sequence of these tasks as shifts in such a way that every task must be assigned to a shift without overlapping. In real-world situations several additional constraints need to be considered, which makes large practical problems challenging to be solved efficiently. In practice it is also an important request with respect to a public transportation scheduling system to offer several versions of quasi-optimal solutions. In this paper we present an efficient driver scheduling solution methodology which is flexible in the above sense.     

Limits of random trees

Local convergence of bounded degree graphs was introduced by Benjamini and Schramm [2]. This result was extended further by Lyons [4] to bounded average degree graphs. In this paper, we study the convergence of a random tree sequence (T _n ), where the probability of a given tree T is proportional to $\prod_{v_{i}\in V(T)}d(v_{i})!$ . We show that this sequence is convergent and describe the limit object, which is a random infinite rooted tree.     

Polynomial identities of bicommutative algebras,Lie and Jordan elements

ABSTRACT

An algebra with identities a(bc)?=?b(ac), (ab)c?=?(ac)b is called bicommutative. We construct list of identities satisfied by commutator and anti-commutator products in a free bicommutative algebra. We give criterions for elements of a free bicommutative algebra to be Lie or Jordan.